The six-time Gujarat MLA, who enjoys influence among tribals in parts of Gujarat, attacked the BJP, saying demonetisation and the Goods and Services Tax (GST) have "destroyed" the economy.
He also claimed that the Sardar Sarovar Dam inaugurated by Prime Minister Narendra Modi yesterday would not be of much help to the common man.
"We will ally with the Congress and also other parties like the Left. We will also try to have a tie-up with Hardik Patel," he told a press conference here.
The state polls are slated for later this year.
The Yadav faction had yesterday declared the Bihar Chief Minister Nitish Kumar's election as the party chief as void and appointed Vasava as its acting chief.
Asked about Mr Kumar's position in the party, Vasava claimed he had left the organisation.
With a big majority of the party's elected members and office bearers backing Kumar following Mr Yadav's challenge to his leadership, Mr Vasava claimed that Members of Legislative Assemblies (MLAs) and Members of Parliament (MPs) have no role and insisted that his group has adequate support within the party.
Mr Kumar and leaders supporting him have refrained from commenting on yesterday's developments.
They have already approached the Rajya Sabha chairman to disqualify Yadav and another party MP Ali Anwar over their alleged anti-party activities.
Mr Yadav came out against Mr Kumar after the latter dumped the RJD and the Congress and joined hands with the BJP in a matter of hours, saying that he could not run a government in Bihar with the RJD as its leader and then deputy chief minister Tejashwi Yadav had not come clean on corruption charges.